High barrier semi-crystalline polyesters involving nature occurring pyridine structure towards sustainable food packaging
نویسندگان
چکیده
This work contributes to develop bioplastics with high gas barrier properties. Here we reported a new bio-based semi-aromatic polyester poly(decylene 2,6-pyridinedicarboxylate) (PDePD26) for food packaging applications, synthesized from 2,6-pyridinedicarbonyl dichloride (PDD26) and 1,10-decanediol (DD) by traditional polycondensation reaction. Two analogs, 2,5-pyridinedicarboxylate) (PDePD25) isophthalate) (PDeIP) were also synthesized. The obtained polyesters confirmed semicrystalline M w ‾ higher than 50 000 g mol −1 . structure polarity geometric symmetry of the aromatic moieties revealed be efficient tools tailor ability crystallization, then affect thermal, mechanical transport performances. containing pyridine rings (PDePD26 PDePD25) showed lower thermal degradation temperatures (341 304 °C) one phenyl (PDeIP, 371 °C), but T , m crystallinities higher. PDePD26 displayed preferred strength ( σ b = 12.5 ± 4.8 MPa) elongation ε 25.0 6.0%) at break. highest properties much better PLA comparable amorphous PET. • A was 2,6-pyridinedicarboxylic acid. performance proposed application. film had polar enhanced polymer crystallization asymmetric favored
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ژورنال
عنوان ژورنال: Polymer
سال: 2022
ISSN: ['1873-2291', '0032-3861']
DOI: https://doi.org/10.1016/j.polymer.2022.124790